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Recording of LIFE Infoday session(edition Call 2021- content valid also for call 2022) DT19 and DT20 assess the effect of including and excluding, respectively, only deaths for which COVID-19 was listed as the underlying cause on the death certificate. Before COVID-19, e0 in Brazil lagged behind many countries in Asia, Europe and the Americas. PubMed Central . D.I.C., M.I.J., and E.N.G.M. Lancet Glob. & Garenne, M. The 1918 influenza epidemics effects on sex differentials in mortality in the United States. endobj A life cycle assessment was used to compare the routes that involved (i) no sonication, (ii) sonication for 1 min (2.5% w/v) and (iii) sonication for 2 min (5.0% w/v), including the workup steps,. Overall, the viscoelastic properties of the synthesized PSAs suggest they would be useful for applications such as removable general-purpose adhesives, including tapes, bandages, and sticky notes. In the meantime, to ensure continued support, we are displaying the site without styles Jul 13, 2021 Nature and Biodiversity ID:LIFE-2021-SAP-NAT-NATURE Type of action: [object Object] Objective: To contribute to European Union objectives for the protection, maintenance and restoration of the Union's natural capital in its marine, freshwater and terrestrial ecosystems. S3). Google Scholar. The Guardian. Wernet, G. et al. While catalytic depolymerization methods20 can, in principle, proceed without side-chain degradation, they have not yet been demonstrated for commercial sources of polyacrylic acid. The South was the last region to be severely hit by COVID-19 in 2020 (ref. Carvalho, C. A., Viola, P. C. A. F. & Sperandio, N. How is Brazil facing the crisis of food and nutrition security during the COVID-19 pandemic? Natl Acad. and S.K. J. Phys. Sustainable polycarbonate adhesives for dry and aqueous conditions with thermoresponsive properties, Recent advances in biodegradable polymers for sustainable applications, Hydroplastic polymers as eco-friendly hydrosetting plastics, Moisture outgassing from siloxane elastomers containing surface-treated-silica fillers, End-of-life upcycling of polyurethanes using a room temperature, mechanism-based degradation, Recyclable thermoset hyperbranched polymers containing reversible hexahydro-s-triazine, Water-processable, biodegradable and coatable aquaplastic from engineered biofilms, Packaging materials with desired mechanical and barrier properties and full chemical recyclability, https://www.alliedmarketresearch.com/pressure-sensitive-adhesives-market, https://www.statista.com/statistics/282732/global-production-of-plastics-since-1950, https://www.epa.gov/sites/production/files/2019-11/documents/2017_facts_and_figures_fact_sheet_final.pdf, https://www.ellenmacarthurfoundation.org/publications/the-new-plastics-economy-rethinking-the-future-of-plastics-catalysing-action, https://www.futuremarketinsights.com/reports/super-absorbent-polymer-market, https://www.petrochemistry.eu/wp-content/uploads/2018/01/150727_EBAM-Eco-profile-Acrylic-Monomers-1.pdf, http://creativecommons.org/licenses/by/4.0/, Closed-loop chemical recycling of cross-linked polymeric materials based on reversible amidation chemistry, Functional Acrylate Polymer Synthesis: Postpolymerization Modification Approach. Characterisation of the first 250,000 hospital admissions for COVID-19 in Brazil: a retrospective analysis of nationwide data. Clin. In a previous paper, we described the spatiotemporal patterns of the spread of COVID-19 cases and deaths in Brazil18. An estimated 6.3 billion metric tons of post-consumer polymer waste has been produced, with the majority (79%) in landfills or the environment. 2 0 obj U.S. Patent Application 2021/0054161 A1 (February 25, 2021). LIFE-2021-SAP-NAT-NATURE Nature and Biodiversity LIFE-2021-SAP-NAT-GOV Nature Governance Each project application under the call must address only one of these topics. and S.K. The adhesive properties of the synthesized polyacrylates were evaluated using rheology and analyzed with respect to Changs viscoelastic window (VW), which classifies different adhesive types48. In the first 4 months of 2021, COVID-19 deaths represented 107% of the total 2020 figures. S2). c, Bivariate choropleth map of the estimated change in e0 and e65 in 2020 based on the difference from life tables calculated for 2019 and 2020 by state. Inicio / Programas UE / LIFE2027 / LIFE-2021-SAP-NAT-GOV (LIFE-2021-SAP-NAT-GOV) - NATURE GOVERNANCE. B., Bell, J. e65 declined by a larger percentage for males than females in all states, reflecting mens higher risks of dying from COVID-19 (ref. We calculated the correlation between the speed of the spread of COVID-19 deaths (measured by the locational Hoover Index)18 and the decline in e0. Governors in that region imposed the most rigorous measures of physical distancing, in direct opposition to recommendations from the President14. "Climate action". Self-wetting adhesive composition. Am. These records, aggregated at the state level, are publicly available by date on the website (https://brasil.io/covid19/). A facile and highly efficient strategy for esterification of poly(meth)acrylic acid with halogenated compounds at room temperature promoted by 1,1,3,3-tetramethylguanidine. From these studies, we conclude that the quantitative esterification of the polymer results from the hydrophobic reaction environment created by the polymer backbone and the 2-ethylhexanol solvent. Sonication has previously been used to chain-shorten high-molar mass polymers with various backbone architectures31,32, including polyacrylic acid33, and has been used at scale34. The superstar forward is not taking anything for granted on her return to netball. Sade Pblica 36, e00115320 (2020). 7 April 2022 - Full Proposal. SAP Certified with fifteen years of SAP development experience in UK and New Zealand. endobj B 121, 36263635 (2017). Therefore, COVID-19 sequelae might shorten individual lifespan. Because this recycling method should be amenable to waste polymer as the feedstock, it offers a more sustainable alternative to diaper disposal in a landfill or incineration. When acetic acid was reacted with 2-ethylhexanol/water, we observed a 94% conversion. Liang, L. et al. For all intervals except ages 01, 15 and 90+, the interval length n is 5 years wide. Get the most important science stories of the day, free in your inbox. Science 372, 815821 (2021). (Wiley-VCH Verlag GmbH & Co, Weinheim, 2020). sub-programme "Transition to clean energy". https://doi.org/10.1053/j.seminoncol.2020.12.002 (2021). Across states, the largest declines were estimated for Amazonas (3.14 years), Amap (2.46 years) and Par (2.44 years). Among states, Amazonas lost 60.4% of the improvements in e0 since 2000. S1). 32, 290299 (2016). Third, reports of long-term consequences of COVID-19 among survivors continue to emerge32,33, including fatigue and neurological, pulmonary and cardiovascular complications, among others. Science 372, 821826 (2021). We demonstrate herein that our open-loop recycling approach to pressure-sensitive adhesives from superabsorbent polymers outcompetes the petroleum-derived syntheses on nearly every metric, including global warming potential and cumulative energy demand. The authors thank Procter and Gamble (P&G) for supporting this work, as well as Ryan Hayes and Jonah Vilseck for assisting with simulations, Edwin Zishiri for assisting with synthesis, Gary Gilbertson, Bill Begley, and Yiping Sun for performing SEC on the PSAs, and Prof. Brian Love for his intellectual contributions. "Environment" area. In Latin America, at least four countries experienced secular mortality declines at earlier dates: Argentina, Uruguay, Costa Rica and Cuba9. Chubarova, E. V., Melenevskaya, E. Y. In both countries, the pandemic response in 2020 was disparate regionally, with lamentable national coordination3,4, resulting in a high and unequal mortality burden5,6. C.M.T. Proven ability to identify and interpret a. http://www.genomahcov.fiocruz.br/tabela-de-dados/ (2021). We approximated the population at risk in 2021 by interpolating IBGE population projections to the mid-analysis period (1 March 2021). The state gap remained roughly the same for both e0 and e65 (Fig. X.iieS(,& Brazil continues to face a challenging situation. The impact of COVID-19 on people with diabetes in Brazil. These results suggest that the substrate hydrophobicity also favors conversion to the ester. Fundao Oswaldo Cruz. 1). Google Scholar. Brasil, Grandes Regies e Unidades da Federao 2010. in Estudos e Pesquisas. EXPERIENCE 15 years of experience in Shared Services, BPO, Finance, Business and Investment. Soil Environ. Google Scholar. We also thank Prof. Charlie Brooks for providing GPU computing resources. In January 2021, Manaus witnessed one of the most tragic scenarios of overwhelmed hospital capacity, running out of not only hospital beds but also oxygen22. Polym. H2SO4 with heating (Fig. LIFE-2022-SAP-NAT Nature and Biodiversity - Standard Action Projects (SAP) Page contents Details Description Details Status Closed Publication date 17 May 2022 Opening date 17 May 2022 Deadline model Single-stage Deadline date 04 October 2022, 17:00 (CEST) Funding programme Programme for the Environment and Climate Action (LIFE) Department In closed-loop chemical recycling, chemical transformations are used to cleave the polymer into its monomers (depolymerization), or to create a polymer with equivalent function12. To do this, we multiplied the age group-specific and sex-specific mortality rates from 2019 from each state by the corresponding projected population for March 2021. defined the methodology. THIS GRANT IS CURRENTLY CLOSED. Google Scholar. To probe the role of both solvent and substrate hydrophobicity, we used two different substrates (acetic versus undecanoic acid) and solvents (ethanol versus 2-ethylhexanol). are employees at P&G. Closed-loop chemical recycling via depolymerization to monomer is also not currently feasible for these superabsorbent materials because side-chain degradation outcompetes depolymerization. Fundao Oswaldo Cruz. It was here that Sam, my husband, turned to me and said, 'This could . The evergreen broadleaved shrubs were shorter in height (3.06 0.99 m) than palm-leaved life forms (19.29 5.39 m). - Experienced in end-to-end order management process using SAP <br>- More than fourteen (14) years of experience on data analysis, which provides strategic and tactical support to Real Estate documents from various counties in the United States<br>- Self-motivated, results-oriented, and able to work with minimal supervision<br>- Possess proven problem solving abilities and very strong . For 2021, as the base case scenario, we calculated the number of deaths that would occur in the absence of COVID-19 (\({\,}_n^ \ast D_x\)). 34, 189200 (1991). FaterSMART. a, Change (in years) in the femalemale gap in e0 and e65 based on the difference from life tables calculated for 2019 and 2020 by state and sex. Health 9, e782e792 (2021). Jennifer Sargent was the primary editor on this article and managed its editorial process and peer review in collaboration with the rest of the editorial team. 8). Il 13 luglio stato aperto il primo invito a presentare proposte nell'ambito del nuovo programma LIFE 2021-202 7, che comprende quattro sottoprogrammi: natura e biodiversit, economia circolare e qualit della vita, | Saiba mais sobre as conexes, experincia profissional, formao . Of the gains achieved in e0 in Brazil over 2 decades, 19% were lost due to COVID-19 (Supplementary Table 8). Baqui, P., Bica, I., Marra, V., Ercole, A. Int. A life cycle assessment demonstrates that the adhesives synthesized via this approach outcompete the same materials derived from petroleum feedstocks on nearly every metric, including carbon dioxide emissions and cumulative energy demand. Therefore, we estimated the provisional decline in life expectancy in 2021 thus far; this estimate is based on the DT19 method noted earlier but, in this case, adding confirmed 2021 COVID-19 deaths to the deaths expected among those who did not die of COVID-19, who are assumed to be subject to 2019 mortality rates for the remainder of 2021 (Supplementary Table 11). The ecoinvent database version 3 (part I): overview and methodology. Effect of economic recession and impact of health and social protection expenditures on adult mortality: a longitudinal analysis of 5565 Brazilian municipalities. Assuming that death rates would have been equal to 2019 all-cause rates in the absence of COVID-19, COVID-19 deaths in 2021 have already reduced e0 in 2021 by 1.8 years, which is slightly larger than the reduction estimated for 2020 under similar assumptions. Commercial polymers are ubiquitous, with a global annual production of approximately 368 million metric tons1, with about 75% of plastics disposed of after a single use2. M.C.C. In Ullmans Encyclopedia of Industrial Chemistry. Briefly, nonamers of polyacrylic acid were used as a model system along withbutanol Comparison of the reaction free energies was made between the first esterification and the final esterification. For many polymers, recycling via mechanical processes is not feasible and these materials are destined for landfills or incineration. Nat. (John Wiley & Sons, Inc., 2003). The resulting materials exhibit low-to-medium storage and loss moduli, and as such, are applicable as general-purpose adhesives. Programme: Programme for Environment and Climate Action (LIFE) . Fornof, A. R. et al. We calculated the probability of surviving from age x to age x + n (npx), the probability of dying between age x and x + n (nqx) and the average person-years lived in the interval by those dying in the interval (nax): where * indicates that the measure is from the life table that does not contain COVID-19 as a cause of death. Reaction conditions for base-mediated and acid-catalyzed decrosslinking reactions with LCA comparison. 9, 407418 (2021). Phillips, T. Covid eruption in Brazils largest state leaves health workers begging for help. PubMedGoogle Scholar. Bystryak, S., Santockyte, R. & Peshkovsky, A. S. Cell disruption of S. cerevisiae by scalable high-intensity ultrasound. Our results point to an overall widening of the femalemale gap in e0 of 0.6 years in Brazil (9.1% increase). Google Scholar. Eng. State acronyms by region: North: AC=Acre, AP=Amap, AM=Amazonas, PA=Par, RO=Rondnia, RR=Roraima and TO=Tocantins; Northeast: AL=Alagoas, BA=Bahia, CE=Cear, MA=Maranho, PB=Paraba, PE=Pernambuco, PI=Piau, RN=Rio Grande do Norte and SE=Sergipe; Center-West: DF=Distrito Federal, GO=Gois, MT=Mato Grosso and MS=Mato Grosso do Sul; Southeast: ES=Esprito Santo, MG=Minas Gerais, RJ=Rio de Janeiro and SP=So Paulo; South: PR=Paran, RS=Rio Grande do Sul and SC=Santa Catarina. endobj 9w%?>Jb(o.IACt"`. Cancer diagnosis in Brazil in the COVID-19 era. The dataset provides the age and sex structure of hospitalized COVID-19 deaths, and frequent updates are made publicly available by the Ministry of Health (https://opendatasus.saude.gov.br/nl/dataset). Chemically recyclable polymers: a circular economy approach to sustainability. Nature and Biodiversity ). https://www.theguardian.com/world/2021/jan/14/brazil-manaus-amazonas-covid-coronavirus (2021). The COVID-19 pandemic in Brazil: analysis of supply and demand of hospital and ICU beds and mechanical ventilators under different scenarios.

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